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一系列(μ-巯基)(μ-烃硫)六羰基二铁(A),(μ-HS)(μ-RS)Fe_2(CO)_6,同甲基乙烯基酮能发生Michael型反应,生成非对称型合β-酮乙基新颖铁硫原子簇络合物,(μ-RS)(μ-CH_3CCH_2CH_2S)Fe_2(CO)_6。此反应具有自诱导,碱诱导和酸抑制的特点。
A series of (μ-mercapto) (μ-hydrocarbon) thiocarbonyl iron (A), (μ-HS) (μ-RS) Fe_2 (CO) (Μ-RS) (μ-CH_3CCH_2CH_2S) Fe_2 (CO) _6 with asymmetric β-keto ethyl novel iron-sulfur cluster complexes. This reaction has the characteristics of self-induction, alkali induction and acid suppression.