Application of simultaneous determination of inorganic ionic species by advanced ion chromatography

来源 :色谱 | 被引量 : 0次 | 上传用户:fch_ray
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In this study,our recent work on advanced ion chromatographic methods for the simultaneous determination of inorganic ionic species such as common anions ( SO42 -,Cl- and NO3- ) and cations (Na+,NH4+,K+,Mg2+,and Ca2 + ),nutrients ( phosphate and silicate) and hydrogen ion/alkalinity are summarized first.Then,the applications using these methods for monitoring environmental water quality are also presented.For the determination of common anions and cations with nutrients,the separation was successfully performed by a polymethacrylate-based weakly acidic cation-exchange column of TSKgel Super IC-A/C ( Tosoh,150 mm x 6.0 mm i.d.) and a mixture solution of 100 mmol/L ascorbic acid and 4 mmol/L 18-crown-6 as acidic eluent with dual detection of conductivity and spectrophotometry.For the determination of hydrogen ion/alkelinity,the separation was conducted by TSKgel ODS-100Z column (Tosoh,150 mm ×4.5 mm i.d.) modified with lithium dodecylsulfate and an eluent of 40 mmol/L LiCl/0.1 mmol/L lithium dodecylsulfate/0.05 mmol/L H2SO4 with conductivity detector.The differences of ion concentration between untreated and treated wastewater showed the variation of ionic species during biological treatment process in a sewage treatment plant.Occurrence and distribution of water-quality conditions were related to the bioavailability and human activity in watershed.From these results,our advanced ion chromatographic methods have contributed significantly for water quality monitoring of environmental waters.
其他文献
在密度泛函理论框架下,用广义梯度近似(GGA)的方法研究GemCn(m+n=7)团簇的基态几何结构,系统计算它们的基态束缚能Be(au)、最高占据轨道(HOMO)与最低未占据轨道(LUMO)之间的
采用静电纺丝技术制备了PVP/[La(NO3)3+Fe(NO3)3]复合纳米纤维,在700℃下焙烧得到LaFeO3纳米纤维,再以CS2作为硫源进行硫化,成功制备了La2Fe2S5亚微米棒。利用XRD,SEM,EDS,宽
为了实现对Ti—Si—N纳米薄膜的原子尺度仿真,本文根据第一原理计算结果,采用Morse势对Ti,Si,N之间作用势进行拟合,并利用TiN二维拉伸模型进行验证.拟合结果表明,采用简单作
运用量子力学PM3方法模拟α-环己基扁桃酸((R/S)-CHMA)与β-环糊精(β-CD)的主客体相互作用,探讨(R/S)-CHMA在β-CD上的手性识别机理。模拟结果能够准确预测色谱出峰顺序从而
目的 利用Mimox软件分析幽门螺杆菌Catalase蛋白模拟表位的性质,并与手工比对结果进行比较.方法 将源于噬菌体随机肽库筛选技术获得的5个Catalase模拟表位输入Mimox网站,参数
采用LRC电桥、谐振法和干涉法分别测量了磷酸二氢钾(KDP)晶体的相对介电常数、弹性应变常数和压电应变常数,并与文献中的相应数值作比较。该文实验测到KDP晶体的弹性柔顺系数
为探索常波长模式的超小角中子散射(USANS)谱仪技术,在广泛调研的基础上对USANS谱仪作原理设计,用Simres、NOP程序以及解析方法,进行了单色器/分析器的切槽单晶设计,谱仪前置
介绍了一种量子元胞自动机(QCA)可编程逻辑阵列结构,该结构可用于实现量子元胞自动机大规模可编程逻辑电路,采用QCADesigner仿真软件研究了元胞缺失、移位缺陷和未对准缺陷对
设计3组化容补水泵模型,运用Pro/E建立三维模型,由CFD软件仿真,并对水力模型进行试验,对比试验与仿真结果,获取最优模型。通过ANSYS Workbench建立CFD与Static Structural(静
利用密度泛函理论中的B3LYP/LanL2DZ方法对PdnZr(n=2~8)团簇的几何结构、稳定性、电子性质进行了研究.在优化出的结构的基础上,讨论了PdnZr(n=2~8)团簇的生长模式,计算了团簇基