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The title complex [Cu2(Sams)2(H2O)2(bipy)]·(H2O) 1 (H2Sams = N-(2-hydroxybenzy) aminomethanesulfonic acid, bipy = 4,4'-bipyridine) has been synthesized by the reaction of Cu-(CH3COO)2·H2O, H2Sams and 4,4'-bipyridine in aqueous methanol.