论文部分内容阅读
利用2-氰基吡啶与叠氮阴离子,在开放体系、温和条件下发生Demko-Sharpless原位配体反应,合成得到铁四氮唑配合物[Fe(2-PTZ)2(H2O)2]。该配合物为单核结构,其晶体属单斜晶系,P21/c空间群。配合物通过分子间的氢键及错位的面对面π-π堆积作用形成三维超分子体系。
By using 2-cyanopyridine and azide anions, the iron-tetrazolium complex [Fe (2-PTZ) 2 (H2O) 2] was synthesized under the open system and under mild conditions. The complex is a mononuclear structure, the crystal is monoclinic, P21 / c space group. The complex forms a three-dimensional supramolecular system by intermolecular hydrogen bonding and dislocation-facing π-π stacking.