论文部分内容阅读
LiMn_ 1.8Co_ 0.2O_ 3.95F_ 0.05 powder was prepared by heating the ignited LiMn_ 1.8Co_ 0.2O_ 3.95F_ 0.05 precursor gel using lithium acetate, magnesium acetate, cobalt acetate, lithium fluoride, citric acid and glycol as raw materials. The influence of the calcination temperature on the structural and electrochemical properties of LiMn_ 1.8Co_ 0.2O_ 3.95F_ 0.05 was investigated by X-ray diffraction, scanning electron microscopy, and galvanostatic charge-discharge experiments. The powders prepared under different conditions are of good crystallinity. The discharge capacity of LiMn_ 1.8Co_ 0.2O_ 3.95F_ 0.05 powder increased from 92 mAh/g to 105mAh/g as the calcination temperature increased from 750 ℃ to 850 ℃. The capacity of LiMn_ 1.8Co_ 0.2O_ 3.95F_ 0.05 heated at 750 ℃, 800 ℃, 850 ℃ for 4 hours remained at 95.2%, 97%, 94.2%, respectively, after being cycled 20 times, suggesting that the multiple substitution of Co and F for Mn and O results in a good cycling behavior.
LiMn_1.8Co_0.2O_3.95F_0.05 powder was prepared by heating the ignited LiMn_1.8Co_0.2O_3.95F_0.05 precursor gel using lithium acetate, magnesium acetate, cobalt acetate, lithium fluoride, citric acid and glycol as raw materials. The influence of the calcination temperature on the structural and electrochemical properties of LiMn 1.8 Co 0.2O 3.95F 0.05 was investigated by X-ray diffraction, scanning electron microscopy, and galvanostatic charge-discharge experiments. The discharge prepared under different conditions are of good crystallinity. The discharge capacity LiMn 1.8 Co 0.2 Mo 3.95 F 0.05 0.05 at 750 C at 800 ° C. The capacity of LiMn 1.8 Co 0.2 Mo 3.95 F 0.05 was increased from 92 mAh / g to 105 mAh / g as the calcination temperature increased from 750 ° C to 850 ° C. , 850 ° C for 4 hours remained at 95.2%, 97%, 94.2%, respectively, after being cycled 20 times, suggesting that the multiple substitution of Co and F for Mn and O results in a good cycling behavior.