表面活性剂溶液的各种物理性质(如界面张力、当量电导、渗透压等)在临界胶团浓度(CMC)狭小的浓度区间的突变引出了胶团的概念,同时也给出了胶团常数CMC的测定方法.近来,Zana还进一步指出,表面活性剂对一些非振荡的化学反应的影响在CMC附近也有突变.由此,我们很自然会想到,在CMC附近改变表面活性剂浓度,则其对振荡反应的影响是否也有突变?也就是说,在胶团的形成过程中,胶团与单体两形态组成的变化对振荡反应是否有影响?此问题一直未有人注意到. The various physical properties (such as interfacial tension, equivalent conductance, osmotic pressure, etc.) of the surfactant solution in the narrow range of critical micelle concentration (CMC) lead to the concept of micelles, and also gives the micelle constant CMC Recently, Zana further pointed out that the effect of surfactants on some non-oscillatory chemical reactions is also mutated around the CMC, and it is quite natural for us to think that changing the surfactant concentration near the CMC Is there any mutation in the oscillatory reaction? In other words, whether the change of the two micelles and the monomer composition has an effect on the oscillatory reaction during the formation of micelles has never been noticed.