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The uniform layered LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries was prepared by using (Ni1/3Co1/3Mn1/3)C2O4 as precursor synthesized via oxalate co-precipitation method in air. The effects of calcination temperature and time on the structure and electrochemical properties of the LiNi1/3Co1/3Mn1/3O2 were systemically studied. XRD results revealed that the optimal calcination conditions to prepare the layered LiNi1/3Co1/3Mn1/3O2 were 950°C for 15 h. Electrochemical measurement showed that the sample prepared under the such conditions has the highest initial discharge capacity of 160.8 mAh/g and the smallest irreversible capacity loss of 13.5% as well as stable cycling performance at a constant current density of 30 mA/g between 2.5 and 4.3 V versus Li at room temperature.
The uniform layered LiNi1 / 3Co1 / 3Mn1 / 3O2 cathode material for lithium ion batteries was prepared by using (Ni1 / 3Co1 / 3Mn1 / 3) C2O4 as precursor synthesized via oxalate co-precipitation method in air. The effects of calcination temperature and time on The structure and electrochemical properties of the LiNi1 / 3Co1 / 3Mn1 / 3O2 were systemically studied. XRD results revealed that the optimal calcination conditions to prepare the layered LiNi1 / 3Co1 / 3Mn1 / 3O2 were 950 ° C for 15 h. Electrochemical measurement showed that the sample prepared under such conditions has the highest initial discharge capacity of 160.8 mAh / g and the smallest irreversible capacity loss of 13.5% as well as stable cycling performance at a constant current density of 30 mA / g between 2.5 and 4.3 V versus Li at room temperature.