二硫代氨基甲酸酯是一类重要的杀菌剂和具有多样反应性能的合成试剂。为此曾报道了它的多种合成方法。其中以两步合成法最为普遍,即首先将胺、二硫化碳及氢氧化钠水溶液进行反应生成二硫代氨基甲酸钠水溶液,再进一步分离出固体钠盐,继而在有机溶剂如醇、二甲基甲酰胺中与卤代烃烃化,最后生成二硫代氨基甲酸酯。 Dithiocarbamates are a class of important fungicides and synthetic reagents with diverse reactivity. To this end, it has reported a variety of synthetic methods. Which is the most common two-step synthesis, that is, the first reaction of ammonia, carbon disulfide and aqueous sodium hydroxide to form an aqueous solution of sodium dithiocarbamate, followed by further separation of the solid sodium salt, followed by an organic solvent such as alcohol, dimethylformamide With halocarbons to form dithiocarbamates.