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A new ternary neodymium zirconium sulfide Nd_2ZrS_5 was synthesized by high-temperature solid-state reaction and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group Pnma(No. 62) belonging to the Y_2HfS_5 structure-type with a = 11.461(4), b = 8.009(3), c = 7.315(3) ?, Z = 2 and V = 671.5(4) ?~3. Its structure features NdS_8 and ZrS_7 polyhedra-constructed a 3-D network. The data of magnetic susceptibility indicate its antiferromagnetic-like behavior without magnetic order down to 2 K.
A new ternary neodymium zirconium sulfide Nd_2ZrS_5 was synthesized by high-temperature solid-state reaction and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group Pnma (No.62) belonging to the Y_2HfS_5 structure-type with a = 11.461 (4), b = 8.009 (3), c = 7.315 (3) ?, Z = 2 and V = 671.5 (4)? ~ 3. Its structure features NdS_8 and ZrS_7 polyhedra-constructed a 3-D network The data of magnetic susceptibility indentation of its antiferromagnetic-like behavior without magnetic order down to 2 K.