NSR催化剂12CaO 7Al2O3/10%K中水对NO还原性能的影响

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主要讨论在不同反应温度和不同水蒸汽浓度下,新型的NOx储存-还原催化剂12CaO·7Al2O3/10%K(简称C12A7/K)中水的存远訬O还原性能的影响.研究结果表明,当存在1.2%水蒸汽,并低于500 ℃时,NO转化率和N2的选择性均降低,水蒸汽的存在对催化剂低温区的活性起到较明显的抑制作用;而温度高于500 ℃时,此抑制作用则基本消失,说明此时C12A7/K催化剂的水热稳定性较好.FT-IR结果证明储存NOx后的C12A7/K样品中形成了NO3/NO2的反应中间物种,用H2还原则可消除中间物种,以N2等形式放出.
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