论文部分内容阅读
异丁烯醛化反应中生成两种醛:3-甲基丁醛(以下简称MB)和2,2—二甲基丙醛(以下简称DMP)。我们曾报导YCCo_3(CO)_9型三核羰基钴簇是一类新型的烯烃醛化催化剂。尤其对于空间位阻较大的烯烃与钴膦催化剂相比,优越性更大。本文研究了在异
Two aldehydes are formed in the methacrolein reaction: 3-methylbutyraldehyde (hereinafter referred to as MB) and 2,2-dimethylpropionaldehyde (hereinafter referred to as DMP). We have reported that YCCo_3 (CO) _9 type trinuclear cobalt carbonyl cluster is a new type of olefin hydroformylation catalyst. In particular, sterically hindered olefins are superior to cobalt phosphine catalysts. This article studies differences