NMR Revealed Activated Alumina-Water Interaction

来源 :Wuhan University Journal of Natural Sciences | 被引量 : 0次 | 上传用户:manaijin
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Three different spin-lattice relaxation times (T_1) of water were obtained in activated alumina-water slurry system, which indicate that there exist three states of water: bound water, pore water and bulk water. The chemical shift (δ_H) decreases as the amount of water added to the system increases due to the differences in contribution of these three states of water in the samples. The δ_H value for adsorbed water decreases nearly linearly and T_1 increases with elevating temperature, which result from the decrease in the content of bound water by the increase in thermal motion. Three different spin-lattice relaxation times (T_1) of water were obtained in activated alumina-water slurry system, which indicates that there exists three states of water: bound water, pore water and bulk water. The chemical shift (δ_H) decreases as the amount of water added to the system increases due to the differences in contribution of these three states of water in the samples. The δ_H value for adsorbed water decreases nearly linearly and T_1 increases with elevating temperature, which result from the decrease in the content of bound water by the increase in thermal motion.
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