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在二甲基甲酰胺和水混合溶剂中及在大阳离子Ｍ（Ⅱ）（Ｍ（Ⅱ）＝Ｃｄ（Ⅱ）、Ｈｇ（Ⅱ））的催化下，用分光光度法研究了四苯基卟啉锌Ｚｎ（Ⅱ）ＴＰＰ的生成反应动力学，提出了反应机理：Ｍ（Ⅱ）＋Ｈ２ＴＰＰＫ２Ｍ（Ⅱ）＊Ｈ２ＴＰＰＭ（Ⅱ）＊Ｈ２ＴＰＰ＋Ｚｎ（Ⅱ）ｋ３→Ｚｎ（Ⅱ）ＴＰＰ＋Ｍ（Ⅱ）＋２Ｈ＋Ｚｎ（Ⅱ）＋Ｈ２ＴＰＰＫ１Ｚｎ（Ⅱ）＊Ｈ２ＴＰＰＺｎ（Ⅱ）＊Ｈ２ＴＰＰｋ１→Ｚｎ（Ⅱ）ＴＰＰ＋２Ｈ＋Ｚｎ（Ⅱ）＊Ｈ２ＴＰＰ＋Ｚｎ（Ⅱ）ｋ２→Ｚｎ（Ⅱ）ＴＰＰ＋Ｚｎ（Ⅱ）＋２Ｈ＋研究了温度对反应动力学参数的影响，求得各平衡步的ΔｒＨ０ｍ，ΔｒＳ０ｍ及其他基元反应的活化参数Δ≠Ｈｍ，Δ≠Ｓｍ。
Under the catalysis of the large cation M (II) (M (II) = Cd (II), Hg (II)) in dimethylformamide and water mixed solvents, the photolysis of tetraphenylporphyrin The reaction kinetics of Zn (Ⅱ) TPP was proposed and the reaction mechanism was proposed. The reaction mechanism was as follows: H2 (superscript 2 +) H2TPPK2M (Ⅱ) * H2TPP + Zn (Ⅱ) k3 → Zn (Ⅱ) TPP + (Ⅱ) * H2TPPZn (Ⅱ) * H2TPPk1 → Zn (Ⅱ) TPP + 2H + Zn (Ⅱ) * H2TPP + Zn (Ⅱ) k2 → Zn (Ⅱ) TPP + Zn (Ⅱ) + 2H + The influence of temperature on the kinetic parameters was studied. ΔrH0m, ΔrS0m and activation parameters of other elementary reactions Δ ≠ Hm, Δ ≠ Sm.