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A new compound,N,N’-bis[(1-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-α-furylme-thylidyne]ethylenediimine ((HPMαFP)2en),has been synthesized and characterized by IR spectra,thermogravimetric analysis and single-crystal X-ray diffraction. The title compound crystallizes in a monoclinic system,space group P21/c with a = 10.7485(11),b = 7.6972(8),c = 16.8367(18) ,β = 93.937(2)o,Z = 2,V = 1389.7(3) 3,Dc = 1.340 g/cm3,F(000) = 588.0,μ = 0.091 and S = 1.016. Structural analysis indicates that (HPMαFP)2en exists in an amine-one form. The molecules are well ordered through two intramolecular (N(3)-H(3)···O(1) and C(2)-H(2)···O(1)) and one intermolecular C(3)-H(3)···O(1) hydrogen bonds,leading to the formation of 1D infinite chains. The interactions of these hydrogen bonds contribute to the stabilization of the compound.
A new compound, N, N’-bis [(1-phenyl-3-methyl-5-oxo-4-pyrazolinyl) -α-furylmethyidyne] ethylenediimine ((HPMαFP) 2en), has been synthesized and characterized by IR spectra, thermogravimetric analysis and single-crystal X-ray diffraction. The title compound crystallizes in a monoclinic system, space group P21 / c with a = 10.7485 (11), b = 7.6972 (8), c = 16.8367 β = 93.937 (2) o, Z = 2 V = 1389.7 (3) 3 Dc = 1.340 g / cm3 F (000) = 588.0 μ = 0.091 and S = 1.016 Structural analysis indicates that (HPMαFP) 2en exists in an amine-one form. The molecules are well ordered through two intramolecular (N (3) -H (3) ··· O (1) and C (2) -H )) and one intermolecular C (3) -H (3) ··· O (1) hydrogen bonds, leading to the formation of 1D infinite chains. The interactions of these hydrogen bonds contribute to the stabilization of the compound.