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本文合成和表征了两种新的杂双核配合物：［Ｃｕ（ｏｘｄｎ）Ｎｉ（ｔｍｎ）＿２（ＣｌＯ＿４）＿２（１）和［Ｃｕ（ｏｘｄｎ）Ｎｉ（ｔｍｄ）＿２］（ＣｌＯ＿４）２（２），ｏｘｄｎ代表Ｎ，Ｎ＇－双（３－氨丙基）草酰胺根阴离子；ｔｍｎ为Ｎ．Ｎ．Ｎ＇－四甲基乙二胺；ｔｍｄ表示１．３－丙二胺。测定了配合物（１）的变温磁化率（４～３００Ｋ），其数值用最小二乘法和从自旋哈密顿算符Ｈ＝－２ＪＳ＿１·Ｓ＿２导出的磁方程拟合，求得交换积分Ｊ＝－１１８．８ｃｍ￣（－１）。文中还用Ｋａｈｎ理论解释了这种反铁磁自旋交换作用。
In this paper, two new heterobinary complexes were synthesized and characterized: [Cu (oxdn) Ni (tmn) 2 (ClO_4) _2 (1) and [Cu (oxdn) Ni (tmd) _2] (ClO_4) 2 Oxdn represents N, N’-bis (3-aminopropyl) oxalate anion; N. N’-tetramethylethylenediamine; tmd represents 1.3-propylenediamine. The temperature-dependent magnetic susceptibility (4 ~ 300K) of the complex (1) was measured. The values were fitted by the least square method and the magnetic equation derived from the spin Hamiltonian H = -2JS_1 · S_2. The exchange integral J = -118.8 cm ~ (-1). The Kahn theory is also used to explain this antiferromagnetic spin exchange.