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以DMF和吡啶为溶剂合成了镍的水杨醛缩水杨酰肼Schiff碱(SHSH)的配合物[Ni(py)3(SHSH)]·1.5(py)(其中py代表吡啶),成功培养出了单晶。通过UV、IR、元素分析和X射线衍射等进行了表征。中心镍离子与Schiff碱提供的2个氧原子和1个氮原子以及3个溶剂吡啶的氮原子参与了配位,形成了六配位的变形八面体构型,存在分子内氢键和分子间氢键。晶体属单斜晶系,空间群:P21/n。采用循环伏安法研究了其在吡啶和DMF溶液中的电化学性质。
Ni (py) 3 (SHSH)] 1.5 (py) (where py stands for pyridine) was synthesized from nickel as a salicylaldehyde salicylhydrazide Schiff base (SHSH) using DMF and pyridine as solvent. crystal. Characterization by UV, IR, elemental analysis and X-ray diffraction. The central nickel ion participates in coordination with the nitrogen atoms of two oxygen atoms, one nitrogen atom and three solvent pyridine provided by Schiff base to form a hexacoordinated deformed octahedral configuration with intramolecular hydrogen bonds and intermolecular hydrogen bonds Hydrogen bond. Crystal is monoclinic, space group: P21 / n. Cyclic voltammetry was used to study its electrochemical properties in pyridine and DMF.