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以高纯度的Bi2O3和MoO3为原料,采用电化学方法制备了高质量紫红色Bi-Mo-O单晶,并研究了其输运性质.发现Bi-Mo-O单晶为半导体材料,其电阻随温度的变化可用公式R=R0exp[Ea/(2kBT)]来描述;I-V特性的测量表明,Bi-Mo-O单晶中存在着一个阈值场,当外场低于阈值场时,材料呈现欧姆特性,高于阈值场时,单晶呈现出很强的非线性特征.
High purity Bi-Mo-O single crystal was prepared by electrochemical method using Bi2O3 and MoO3 as raw materials, and their transport properties were studied. It is found that the Bi-Mo-O single crystal is a semiconductor material whose resistance can be described by the formula R = R0exp [Ea / (2kBT)] with the change of temperature. The measurement of the I-V characteristic shows that the Bi- With a threshold field, when the external field is below the threshold field, the material exhibits an ohmic characteristic. Above the threshold field, the single crystal exhibits a strong nonlinear characteristic.