The oxidizability of soil organic carbon(SOC_) influences soil quality and carbon sequestration. Four fractions of oxidizable organic carbon(very labile(C_1), labile(C_2), less labile(C_3) and non-labile(C_4)) reflect the status and composition of SOC_ and have implications for the change and retention of SOC_. Studies of the fractions of oxidizable organic carbon(OC_) have been limited to shallow soil depths and agroecosystems. How these fractions respond at deep soil depths and in other types of land-use is not clear. In this study, we evaluated the vertical distributions of the fractions of oxidizable organic carbon to a soil depth of 5.0 m in 10 land-use types in the Zhifanggou Watershed on the Loess Plateau, C_hina. Along the soil profile, C_1 contents were highly variable in the natural grassland and shrubland I(C_aragana microphylla), C_2 and C_4 contents were highly variable in the natural grassland and two terraced croplands, respectively, and C_3 contents varied little. Among the land-use types, natural grassland had the highest C__1 and C_2 contents in the 0–0.4 m layers, followed by shrubland I in the 0–0.1 m layer. Natural grassland had the highest C_4 contents in the 1.0–4.5 m layers. Natural grassland and shrubland I thus contributed to improve the oxidizability of SOC_ in shallow soil, and the deep soil of natural grassland has a large potential to sequester SOC_ on the Loess Plateau. The oxidizability of soil organic carbon (SOC_) influenced soil quality and carbon sequestration. Four fractions of oxidizable organic carbon (very labile (C_1), labile (C_2), less labile (C_3) and non-labile (C_4) and composition of SOC_ and have implications for the change and retention of SOC_. Studies of the fractions of oxidizable organic carbon (OC_) have been limited to shallow soil depths and agroecosystems. How these fractions respond at deep soil depths and in other types of land In this study, we evaluated the vertical distributions of the fractions of oxidizable organic carbon to a soil depth of 5.0 m in 10 land-use types in the Zhifanggou Watershed on the Loess Plateau, C_hina. Along the soil profile , C_1 contents were highly variable in the natural grassland and shrubland I (C_aragana microphylla), C_2 and C_4 contents were highly variable in the natural grassland and two terraced croplands, respectively, and C_3 contents varied little. Among the land-use types, natural grassland had the highest C__1 and C_2 contents in the 0-0.4 m layers, followed by shrubland I in the 0-0.1 m layer. Natural grassland had the highest C_4 contents in the 1.0-4.5 m layers. Natural grassland and shrubland I thus contributed to improve the oxidizability of SOC_ in shallow soil, and the deep soil of natural grassland has a large potential to sequester SOC_ on the Loess Plateau.