有机过渡金属膦络合物化学在近二十年来获得了飞跃的发展。基于配位体有机膦的配位,对其所形成的络合物结构和反应性的影响,使得均相和非均相催化反应条件大为缓和,收率大为提高,因而得到了广泛的应用。如低压加氢、聚合、羰化、固氮等。本文简述了过渡金属(主要是第八族副族)有机膦络合物结构与均相催化作用的关系,综 Organic transition metal phosphine complex chemistry in the past two decades has made leaps and bounds. Based on the ligand coordination of the organophosphine ligands, the complex structure and reactivity of the complexes formed by the ligands are such that the conditions of homogeneous and heterogeneous catalysis are greatly alleviated and the yield is greatly improved. Thus, a wide range of application. Such as low-pressure hydrogenation, polymerization, carbonylation, nitrogen fixation. This article describes the relationship between the structure and the homogeneous catalysis of organophosphine complexes of transition metals (mainly the eighth subgroup)