Simultaneous Enhancement of Toughness and Strength of Stretched iPP Film via Tiny Amount of β-Nuclea

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Herein,isotactic polypropylene films with small β-nucleating agent content were fabricated via a melt-extrusion-stretched technology with intended “shear-free” in barrel and die.Compared with neat films,the tensile strength,elongation at break and strain energy density at break of iPP film with 0.05 wt% β-nucleating agent are significantly improved by 13.8%,39.6% and 90.6%,respectively,indicating the simultaneously enhanced toughness and strength.Additionally,the β-crystal content gradually increases with increasing β-NA content,while the relative total daughter content of α-and β-crystal exhibits opposite tendency.Moreover,nucleation and crystal growth induced by various β-NA contents are different.This work proves an efficient strategy to enhance mechanical properties of isotactic polypropylene film via controlling elongation flow and addition of appropriate β-NA content.
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