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本文应用憎水亲油的四苯硼酸四苯鉮(tetraphenylarsonium tetraphenylborate简写TPAsTPB)和二卡宝钴酸四丁铵(tetraphenylammonium dicarbolylcobate简写TBADCC)为硝基苯相的基础电解质,进一步考察了水/硝基苯界面上中性大环离子载体所推动的碱金属离子转移,测定了有关络合反应的稳定常数。
In this paper, the hydrophobic / lipophilic tetraphenylarsonium tetraphenylborate (TPTPTPTP) and tetraphenylammonium dicarbolylcobate (TBADCC) were used as the basic electrolytes for the nitrobenzene phase. The effects of water / nitro The interaction of alkali metal ion promoted by the neutral macrocycle on the benzene interface was measured. The stability constant of the complex reaction was determined.