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在考察单一氧化剂H_2O_2、K_2S_2O_8和氧化剂BH、CH对聚合物凝胶破解的基础上,采用了复配氧化剂,利用正交试验法探讨破胶剂的优化组成。评价试验结果表明,60℃环境温度下优选的破胶剂组成为:0.35%H_2O_2、0.4%K_2S_2O_8、0.5%BN、0.6%CN,对粘度为2.3×10~5mPa·s的六次甲基四胺交联的聚丙烯酰胺凝胶的破胶效果理想,在pH=2时,可使凝胶聚合物的破解效率达99%以上,破胶后残液粘度低。岩心模拟试验结果表明,使用该破胶剂破胶前,堵水率98%以上,破胶后渗透率恢复值可达98%以上。能够有效解除聚丙烯酰胺凝胶的堵塞。
On the basis of examining gel cracking of single oxidant H 2 O 2, K 2 S 2 O 8 and oxidant BH and CH, a complex oxidant was used and the optimum composition of breaker was explored by orthogonal test. The evaluation results show that the optimum composition of breaker at ambient temperature of 60 ℃ is 0.35% H 2 O 2, 0.4% K 2 S 2 O 8, 0.5% BN and 0.6% CN, and the viscosity of 2.3 × 10 ~ 5mPa · s hexamethylenetetramine cross-linked polyacrylamide gel gel breaking effect ideal, at pH = 2, the gel polymer can be cracked efficiency of 99% or more, broken gel residue Low viscosity. The core simulation test results show that before using the breaker gel breaker, the water cut rate of 98% or more, broken gel permeability recovery value of up to 98%. Can effectively lift the plug polyacrylamide gel.