A LUMPING KINETICS FOR MODIFIED FT REFORMING PROCESS Ⅱ.EXPERIMENTAL AND KINETICS PARAMETERS ESTIMATI

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:loveqin11
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For determining the kindles parameters of the three-lump modelfor the MFT reforming Process, experiments were carried out in a fixed-bed,plug flow reactor over a commercial HZSM-5 catalyst under the followingoperating conditions: reaction temperature T = 569~638 K, total pressurep=14 atm, H2 flow rate=93 mL.min-1, reactant flow fate=0.5~1.1 mL.min-1,catalyst residence time tc=1~8 h. The best values of the reaction rateconsents and the catalyst deachvation fate constant were obtained by fittingthe experimental results. Statistical analysis results indicated that thekinetics equations are reliable for describing the experimental data.Considering the economic importance of gasoline, some suggestions on howto improve the yield of gasoline were also given. For determining the kindles parameters of the three-lump model for the MFT reforming process, experiments were carried out in a fixed-bed, plug flow reactor over a commercial HZSM-5 catalyst under the following operating conditions: reaction temperature T = 569-638 K, total pressurep = 14 atm, H2 flow rate = 93 mL.min-1, reactant flow fate = 0.5-1.1 mL.min-1, catalyst residence time tc = 1-8 h. The best values ​​of the reaction rateconsents and the catalyst Statistical analysis results indicated that thekinetics equations are reliable for describing the experimental data. Consumption of the economic importance of gasoline, some suggestions on howto improve the yield of gasoline were also given.
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