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在稀醋酸溶液中，微波辐射下壳聚糖与ＣＵ２＋反应制备了壳聚糖Ｃｕ２＋配合物，然后将制得 的配合物与环氧氯丙烷在微波辐射下再进行交联反应后，用稀酸除去Ｃｕ２＋，合成了具有Ｃｕ２＋离子 孔穴的交联壳聚糖树脂．考察了该树脂对Ｃｕ２＋、Ｎｉ２＋、Ｃｏ２＋的吸附性能．实验表明，使用微波辐射 模板法制备具有Ｃｕ２＋离子孔穴的交联壳聚糖树脂，能大大缩短反应时间；制备的树脂在酸性条件下不会发生软化和溶解，重复使用性能亦好；对 Ｃｕ２＋比对Ｎｉ２＋和 Ｃｏ２＋具有较高的吸附容量．
In dilute acetic acid solution, chitosan reacted with CU2 + under microwave irradiation to prepare chitosan Cu2 + complex, and then the resulting complex was reacted with epichlorohydrin under microwave irradiation for further cross-linking reaction. Remove the Cu2 +, cross-linked chitosan resin with Cu2 + ion voids was synthesized. The adsorption properties of Cu2 +, Ni2 + and Co2 + were investigated. The experimental results show that the preparation of crosslinked chitosan resin with Cu2 + ion channels by microwave irradiation can greatly shorten the reaction time; the prepared resin does not soften and dissolve under acidic conditions and has good reusability; the Cu2 + Ni2 + and Co2 + have higher adsorption capacity.