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一种氰根桥联的异金属超分子{Ni(pn)2[Ag(CN)2]2}2被合成并通过单晶X-射线结构表征.该化合物是由配位键和亲银作用(Ag-Ag键)形成的一维链状结构,在室温下其固相和水溶液都表现出由Ag-Ag键引起的荧光性质.
A cyanide bridged heterometallic {Ni (pn) 2 [Ag (CN) 2] 2} 2 was synthesized and characterized by a single crystal X-ray structure. This compound is composed of a coordination bond and an affinity for silver Ag-Ag bond), both its solid phase and its aqueous solution show the fluorescence property caused by the Ag-Ag bond at room temperature.