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利用瓜环外壁的结构导向作用设计并构筑瓜环-金属离子超分子配位聚合物可能成为瓜环配位化学研究的一个新方向。根据瓜环外壁作用类型,研究内容包括:1)瓜环外壁取代烷基推电子效应对瓜环基超分子配位聚合物形成的促进作用;2)瓜环外壁与化合物芳环的相互作用对瓜环基超分子配位聚合物形成的促进作用;3)瓜环外壁与无机阴离子的相互作用对瓜环基超分子配位聚合物形成的促进作用;4)瓜环外壁取代羟基的配位作用对瓜环基超分子配位聚合物形成的促进作用。这些瓜环基超分子配位聚合物可能具有吸附捕集、分离提纯和分析等功能性质。
The use of the structure-oriented effect of the outer ring of melon ring to design and construct guanidinium-metal ion supramolecular coordination polymer may become a new direction for the coordination chemistry of guanidine ring. According to the type of action on the outer wall of cucurbit, the research contents include: 1) the promotion effect of substituting alkyl on the outer wall of cucurbit [6] on the formation of supramolecular coordination polymer of guaiacyl; 2) the interaction between the outer wall of cucumber and the aromatic ring of compound Guanidine ring supramolecular coordination polymer formation promotion role; 3) melon ring outer wall and inorganic anions on the guanidine ring supramolecular coordination polymer formation; 4) melon ring outer wall to replace the hydroxyl coordination On the role of guaiacyl supramolecular coordination polymer formation. These melon ring-based supramolecular coordination polymers may have functional properties such as adsorption-trapping, separation and purification, and analysis.