用镍、铜、银、金四种样品对不同型号的11台X射线光电子能谱仪作了结合能会测。虽然不同仪器对同一个峰测得的结合能可以相差leV以上,但其平均值与已经发表的精确数据符合得比较好。提出了用Ni3d价带边及四种金属的各峰位来校正谱仪结合能读数的建议。样品表面自然沾污C_1s;结合能的测量值有较大的离散性,一般情况下最好不用它作为结合能的内标。 With nickel, copper, silver, gold four samples of different types of 11 X-ray photoelectron spectrometer made a combination of energy can be measured. Although the binding energies measured by different instruments for the same peak can differ by more than leV, their averages are in good agreement with published accurate data. Proposed the use of Ni3d valence band edges and four kinds of metal peaks to calibrate the spectrometer combined readings recommendations. The surface of the sample is naturally contaminated with C 1s; the measured value of binding energy is more discrete, and it is better not to use it as an internal standard for binding energy under normal circumstances.