【摘 要】
：
A novel zinc-rich pigment based on P(St-BA-MAA-SPAA) nano-latex was obtained, which is suitable for the use in hot alkali liquid medium. The nano-latex was synt
【机 构】
：
College of Resources and Environmental Science
【基金项目】
：
Foundation of Communications Department of Hunan Province, China;国家自然科学基金
论文部分内容阅读
A novel zinc-rich pigment based on P(St-BA-MAA-SPAA) nano-latex was obtained, which is suitable for the use in hot alkali liquid medium. The nano-latex was synthesized by active emulsifier latex polymerization method with monomers of styrene(St), butylaerylate (BA), methylacrylic acid(MAA) in the presence of active emulsifier 3-sulfopropylaerylate(SPAA). The synthesis condition and properties of the latex were investigated. And the anti-corrosive property of the resultant zinc-rich coating was studied. The results show that the nano-latex is self-stabilized and has a narrow particle diameter distribution, the average diameter of the latex particles is 71 nm. Zinc powders can be evenly dispersed in the nano-latex, which indicates that the P(St-BA-MAA-SPAA)nano latex can be used as the binder of zinc-rich coating. The resultant zinc-rich coating is able to resist the invasion of hot alkali solution(the temperature is 95 ℃ and the pH value is 14) for 480 h and the exposure time in salt spray is 1 200 h. Moreover, the coating shows good thermal conductivity and static electricity properties, its thermal conductivity and electric resistivity are 21-37 W/(m·K) and 6.7×105-3.5×106 Ω.cm, respectively
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