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The title complex, bis(4 nitrobenzaldehyde thiosemicarbazone) cadmium iodide (C 16H 16CdI 2N 8O 4S 2) crystallizes in the triclinic system, space group P 1 with a=9.632(2), b=11.227(2), c=14.031(3), α= 67.50(3), β= 86.99(3), γ= 66.64(3)°, V=1278.1 3, Z = 2, D c = 2.117gcm -3, F(000) = 772, μ =3 472mm -1 Mo Kα radiation ( λ =0.71073), R = 0.0443, wR= 0.1425 for 4529 observed reflections 〔 I>2σ(I) 〕 of 4731 independent reflections. The result shows that the structure contains CdL 2I 2 (where L = 4 nitrobenzaldehyde thiosemicarbazone) distorted tetrahedral units in which the two ligands are S bonded as monodentate to cadmium ion; the two iodide ions are also coordinated to Cd(II).
The title complex, bis (4 nitrobenzaldehyde thiosemicarbazone) cadmium iodide (C 16 H 16CdI 2N 8O 4S 2) crystallizes in the triclinic system space group P 1 with a = 9.632 (2), b = 11.227 (2), c = 14.031 3 = 78, α = 67.50 (3), β = 86.99 (3), γ = 66.64 (3) °, V = 1278.13, Z = 2, D c = 2.117gcm -3, F (000) = 772 , μ = 3 472 mm -1 Mo Kα radiation (λ = 0.71073), R = 0.0443, wR = 0.1425 for 4529 observed at reflections [I> 2σ (I)] of 4731 independent reflections. The result shows that the structure contains CdL 2I 2 (where L = 4 nitrobenzaldehyde thiosemicarbazone) distorted tetrahedral units in which the two ligands are S bonded as monodentate to cadmium ion; the two iodide ions are also coordinated to Cd (II).