配合物[Co(amb)2(phen)(H2O)]2 CH3OH的合成与表征

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本文主要讨论配合物[Co(mb)(2phen)(H2O)]·2CH3OH(phen是指菲罗啉)的合成和结构表征。对丙烯酰胺基苯甲酸(Hamb)为第一配体,邻菲罗啉(phen)为第二配体,通过固相法与过渡金属醋酸钴反应,合成得到一个结构新颖的配合物,[Co(amb)(2phen)(H2O)]2·CH3OH。并将合成得到的配合物与苯乙烯单体共聚,得到含配合物结构单元的聚合物,为开发配合物-聚合物杂化新材料打下一定的理论基础。 This article mainly discusses the synthesis and structural characterization of the complex [Co (mb) (2phen) (H2O)] · 2CH3OH (phen means phenanthroline). A new ligand was synthesized by the reaction of transition metal cobaltous acetate with solid-phase reaction, using Hamb as the first ligand and phen phenanthrene as the second ligand [Co (amb) (2phen) (H2O)] 2 · CH3OH. And copolymerizing the synthesized complex with the styrene monomer to obtain the polymer containing the structural unit of the complex, which lays a theoretical foundation for the development of the new hybrid-polymer hybrid material.
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