在水醇溶液中合成了配合物[Zn(phen)3].2Bsesa.4H2O(1,phen=邻菲咯啉,BsesaH=苯磺酰牛磺酸),其结构经IR,元素分析和X-射线衍射表征。1属三斜晶系,P-1空间群,晶胞参数:a=1.111 5(3)nm,b=1.415 5(4)nm,c=1.748 6(5)nm,α=80.764(5)°,β=87.237(5)°,γ=88.081(5)°,V=2.711 3(14)nm3,Z=2,Dc=1.478 g.cm-3,μ=0.681 mm-1,F(000)=1 252。1为变形的八面体构型,Zn(Ⅱ)与3个邻菲咯啉配位,未与苯磺酰牛磺酸中的氧原子配位。 The complex of [Zn (phen) 3] 2Bsesa.4H2O (1, phen = phenanthroline and BsesaH = benzenesulfonyl taurine) was synthesized in hydroalcoholic solution. The structure was characterized by IR, elemental analysis and X- Ray diffraction characterization. 1 is a triclinic, P-1 space group with unit cell parameters of a = 1.111 5 (3) nm, b = 1.415 5 (4) nm, c = 1.748 6 ° = β = 87.237 (5) °, γ = 88.081 (5) °, V = 2.7113 (14) nm3, Z = 2, Dc = 1.478 g.cm-3, μ = 0.681 mm-1, ) = 1 252.1 is a distorted octahedral configuration, Zn (Ⅱ) coordinates with 3 phenanthrolines and does not coordinate with oxygen atoms in benzenesulfonyl taurine.