【摘 要】
：
以3-羟基-2-萘甲酰肼和4-二苯氨基苯甲醛为原料,设计合成了一种新型萘甲酰腙铜离子荧光探针L(N′-(4-(二苯胺基)亚苄基)-3-羟基-2-萘酰肼),并通过1H NMR、13C NMR、HR-MS、IR和X射线单晶衍射法对L的结构进行了表征。在H2O/DMSO(V∶V=3∶7,pH=7)溶液体系中,可以高选择性和高灵敏性识别Cu2+。通过质谱法、核磁滴定和DFT计算对L与Cu2+可能的作用机理
【机 构】
：
西华大学理学院,西南石油大学化学化工学院
【基金项目】
：
教育部春晖计划(191630),四川省教育厅项目(18ZB0571)资助。
论文部分内容阅读
以3-羟基-2-萘甲酰肼和4-二苯氨基苯甲醛为原料,设计合成了一种新型萘甲酰腙铜离子荧光探针L(N′-(4-(二苯胺基)亚苄基)-3-羟基-2-萘酰肼),并通过1H NMR、13C NMR、HR-MS、IR和X射线单晶衍射法对L的结构进行了表征。在H2O/DMSO(V∶V=3∶7,pH=7)溶液体系中,可以高选择性和高灵敏性识别Cu2+。通过质谱法、核磁滴定和DFT计算对L与Cu2+可能的作用机理
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