在水热条件下,硝酸(3-氰基吡啶)银以及叠氮化纳反应,成功地组装了一个二维层状银四唑配位聚合物[mono(5-(3-pyridyl)tetrazolato)Ag](1),并对其进行了表征。晶体结构分析表明,化合物1结晶在三斜晶系,其空间群分别为P1(a=0.62608(10)nm,b=0.78498(13)nm,c=0.80584(12)nm,α=75.171(4)°,β=76.653(3)°,γ=68.332(3)°,V=0.35167(10)nm3,Z=2),银的配位环境为四配位并形成略为变形的四面体构型。室温下,化合物1显示强的蓝色荧光(495nm和521nm)。 Under the hydrothermal conditions, the reaction of silver (3-cyanopyridine) nitrate and sodium azide successfully assembled a two-dimensional layered silver tetrazolium coordination polymer [mono (5- (3-pyridyl) tetrazolato) Ag] (1), and characterized. The crystal structure analysis showed that compound 1 crystallizes in the triclinic system with space group P1 (a = 0.62608 (10) nm, b = 0.78498 (13) nm, c = 0.80584 ), Β = 76.653 (3) °, γ = 68.332 (3) °, V = 0.35167 (10) nm3, Z = 2). The coordination environment of silver is tetrahedral and forms a slightly distorted tetrahedron . Compound 1 showed strong blue fluorescence (495 nm and 521 nm) at room temperature.