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Reaction of SmI2(THF)x with 2 equivalents of NaOAr (Ar = C6H2-tert-Bu3-2,4,6)1,2-dimethoxyethane (DME) leads to the ligand-exchange reaction, and a DME-solvated complex of Sm(Oar)2(DME)2 2 was obtained. Complex 1 crystallizes in monoclinic, space group P2