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合成了N -亚水杨基 β -丙氨酸铜 ( 1)和N -亚水杨基牛磺酸铜 ( 2 )两种新配合物 ,用元素分析、摩尔电导、红外光谱、热重差热分析、X -射线粉末衍射对所合成的配合物进行了表征 ,并对X -射线粉末衍射数据进行了指标化。两种配合物的组成分别为Cu(sal- β -ala)·H2 O、Cu(sal-tau)·2H2 O ,X -射线粉末衍射数据指标化结果表明两种配合物均属于正交晶系 ,晶胞参数分别是 :配合物 ( 1)a =1.4 981nm ,b =1.82 4 6nm ,c =2 .1985nm ;配合物 ( 2 )a =0 .94 5 4nm ,b=1.70 92nm ,c=2 .2 2 5 4nm。
Two novel complexes of N - salicylidene β - alanine copper (1) and N - salicylidene taurine (2) were synthesized and characterized by elemental analysis, molar conductance, infrared spectra, The synthesized complexes were characterized by X - ray powder diffraction, thermal analysis and X - ray powder diffraction. The compositions of the two complexes are Cu (sal-β-ala) · H 2 O and Cu (sal-tau) · 2H 2 O. The indexing results of X-ray powder diffraction data indicate that both complexes belong to orthorhombic , The unit cell parameters are: (a) a = 1.4981 nm, b = 1.82 4 6 nm, c = 2.1985 nm; a = 0.94 5 4 nm, b = 1.70 92 nm, c = 2 .2 2 5 4nm.