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Increasing the system capacity and spectral efficiency (SE) per unit bandwidth is one of the ultimate goals for data network designers, especially when using technologies compatible with currant embedded fiber infrastructures.Among these, the polarizationdivision-multiplexing (PDM) scheme, which supports two independent data channels on a single wavelength with orthogonal polarization states, has become a standard one in most state-of-art telecommunication systems.Currently, however, only two polarization states (that is, PDM) can be used, setting a barrier for further SE improvement.Assisted by coherent detection and digital signal processing, we propose and experimentally demonstrate a scheme for pseudo-PDM of four states (PPDM-4) by manipulation of four linearly polarized data channels with the same wavelength.Without any modification of the fiber link, we successfully transmit a 100-Gbs-1 PPDM-4 differential-phase-shift-keying signal over a 150-km single-mode fiber link.Such a method is expected to open new possibilities to fully explore the use of polarization freedom for capacity and SE improvement over existing fiber systems.