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从含有M Fe(M=Mo,Fe)结构单元的双核配合物Mg(DMF)_6[Fe_2S_2Cl_4]及Mg(DMF)_6[FeCl_2·MoS_4]起始,经不同的组合反应,分别得到Fe_4S_4,MoFe_3S_4及Mo_2Fe_2S_4单立方烷簇合物。讨论了这一反应的某些特点并报道了双桥联六配体的Mo_2Fe_2S_4(C_4H_8dtc)_6的晶体与分子结构。
Starting from the binuclear complexes Mg (DMF) _6 [Fe_2S_2Cl_4] and Mg (DMF) _6 [FeCl_2 · MoS_4] containing M Fe (M = Mo, Fe) structural units, Fe_4S_4, MoFe_3S_4 And Mo_2Fe_2S_4 mono-cubic carbon cluster. Some characteristics of the reaction were discussed and the crystal structure and molecular structure of Mo_2Fe_2S_4 (C_4H_8dtc) _6 were reported.