In order to make the static state feedback nonlinear decoupling control law for a kind of missile to be easy for implementation in practice, an improvement is discussed. The improvement method is to introduce a BP neural network to approximate the decoupling control laws which are designed for different aerodynamic characteristic points, so a new decoupling control law based on BP neural network is produced after the network training. The simulation results on an example illustrate the approach obtained feasible and effective.