The paper is related to the error analysis of Multicategory Support Vector Machine (MSVM) classifiers based on reproducing kernel Hilbert spaces. We choose the polynomial kernel as Mercer kernel and give the error estimate with De La Vallée Poussin means. We also introduce the standard estimation of sample error, and derive the explicit learning rate. The paper is related to the error analysis of Multicategory Support Vector Machine (MSVM) classifiers based on reproducing kernel Hilbert spaces. We choose the polynomial kernel as Mercer kernel and give the error estimate with De La Vallee Poussin means. We also introduce the standard estimation of sample error, and derive the explicit learning rate.