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研究了 1 8冠 6与 K2 [Pd( NO2 ) 4 ]的反应 ,并通过元素分析、红外光谱、单晶 X-射线衍射对生成的配合物 [K( 1 8C6) ]2 [Pd( NO2 ) 4 ]( H2 O)进行了表征 .配合物为单斜晶系 ,空间群 P2 1/c.晶体学数据 :a=1 .71 0 4 ( 3) ,b=1 .4859( 3) ,c=1 .5763( 3) nm,β=93.49( 3) 0 ,V=3.9987( 1 4) nm3,Z=4,Dcal.=1 .50 7mg/m3,F( 0 0 0 ) =1 880 ,R1=0 .0 681 .w R2 =0 .1 0 0 4 .在固态 ,配合物具有 [K( 1 8C6) ]2 [Pd( NO2 ) 4 ]( 1 )和 [K( 1 8C6) ]2 [Pd( NO2 ) 4 ]( H2 O) ( 2 )两个基团 ,两者比例为 1 :1 .2中相邻的两个分子通过水分子中的氧原子相连接形成一维链状结构
The reaction of 18 [6] with K2 [Pd (NO2) 4] was studied. The complex [K (1 8C6)] 2 [Pd (NO2) 4] was synthesized by elemental analysis, IR and single crystal X-ray diffraction. 4] (H 2 O). The complex is monoclinic with space group P2 1 / c. The crystallographic data are: a = 1.71 0 4 (3), b = 1.4859 = 1 .5763 (3) nm, β = 93.49 (3) 0, V = 3.9987 (1 4) nm3, Z = 4, Dcal. = 1 .50 7 mg / m3, F (0 0 0) = 1 880, R1 = 0 .0 681 .w R2 = 0 .1 0 0 4. In the solid state, the complex has [K (1 8C6)] 2 [Pd (NO2) 4] (1) and [K (1 8C6)] 2 [Pd (NO 2) 4] (H 2 O) (2) two groups, the ratio of the two is 1: 1 2 two adjacent molecules through the oxygen atoms in water molecules connected to form a one-dimensional chain structure