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A 1-D zigzag chain [Sn(edt)2(p-phenylenediamine)]n (edt = ethane-1,2-thiolate) was synthesized by self-assembly and determined by X-ray structure analysis. The title compound (C10H16N2S4Sn) crystallizes in monoclinic, space group C2/c with a = 16.659(2),