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4′-[4-甲基-6-(1-甲基-1H-苯并咪唑-2-基)-2-丙基-1H-苯并咪唑基甲基]联苯基-2-羧酸(HL)是一种含多个配位点和具有不同配位模式的氮杂环羧酸有机柔性配体,将其与Ag盐自由组合后,合成了磁性、荧光、分子分离、催化、吸附及胶粘剂助剂用新型金属有机配合物{Ag_2(HL)_2(SO_3CF_3)_2}_n,并对其结构和光致发光性能进行了分析。研究结果表明:该配合物是二维层状结构;与配体相比,室温时该配合物表现出较弱的荧光特性(发生了荧光淬灭现象),并且荧光发射峰位置与配体基本相同。
4 ’- [4-methyl-6- (1-methyl-1H-benzimidazol-2-yl) -2-propyl-1H-benzimidazolylmethyl] biphenyl-2-carboxylic acid (HL) is an organic flexible ligand of azacyclocarboxylic acid with multiple coordination sites and different coordination modes. After the free ligands of Ag and Ag are combined, magnetic, fluorescent, molecular separation, catalysis, adsorption (Ag_2 (HL) _2 (SO_3CF_3) _2} _n, a new metal-organic complex for the adhesive agent and its structure and photoluminescence properties were analyzed. The results show that the complex is a two-dimensional layered structure. Compared with the ligand, the complex shows weaker fluorescence (quenching phenomenon) at room temperature, and the fluorescence emission peak position and ligand basic the same.