We report on generating uniaxial negative birefringent compensation films, made of specifically designedpolyimides. These polymers were synthesized via a polycondensation of dianhydride [such as 2, 2’ -bis(3, 4-dicarboxyphenyl)hexafluoropropane dianhydride] and 2, 2’-bis(trifluoromethyl)-4,4’-diaminobiphenyl. The uniaxial negative birefringent (n_x =n_y > n_z) polyimide substrates are achieved using a solution-casting method in conventional solvents, which exhibit thedesirable optical phase retardation [(n_x - n_z)×d] values from 50 to 400 nm varying with the film thickness. In thesepolyimide films, the long chain rigid molecules adopt intrinsic planar orientaion. In detail, the majority of phenylene-imiderings and phenylenes preferentially adopt nearly planar conformations parallel to the film substrae. In addition, these filmsalso possess high transparency (or transmittance) and little color shift. The unique color dispersion curve indicates that thistype of materials is very suitable for the applications in LCDs due to an excellent mimic for the retardation color dispersioncurve with respect to LC molecules. Significantly low in-plane retardation (< 1 nm) allows this new technology based film toachieve sufficiently high contrast ratio while highly negative retardation dramatically suppresses the gray scale inversion toimprove the viewing angle performance in a variety of new mode LCDs. We report on generating uniaxial negative birefringent compensation films, made of specifically designed polyimides. These polymers were molded via a polycondensation of dianhydride [such as 2, 2’-bis (3,4-dicarboxyphenyl) hexafluoropropane dianhydride] and 2, 2’-bis (trifluoromethyl) -4,4’-diaminobiphenyl. The uniaxial negative birefringent (n_x = n_y> n_z) polyimide substrates are achieved using a solution-casting method in conventional solvents, which exhibit the desirable optical phase retardation [(n_x - n_z) × d ] values ​​from 50 to 400 nm varying with the film thickness. In these polyimide films, the long chain rigid molecules adopt intrinsic planar orientations. In detail, the majority of phenylene-imide and phenylenes preferentially adopter nearly planar conformations parallel to the film substrae. In addition, these filmsalso possess high transparency (or transmittance) and little color shift. The unique color dispersion curve indicates that thistype of materials is very suitab Significantly low in-plane retardation (<1 nm) allows this new technology based film to achieve high contrast ratio while highly negative retardation dramatically suppresses the gray scale inversion toimprove the viewing angle performance in a variety of new mode LCDs.