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5. Ethylene Oligomerization to Low Carbon Olefins by a Zirconium Complex Incorporating 8-Quinolinolato

Ethylene Oligomerization to Low Carbon Olefins by a Zirconium Complex Incorporating 8-Quinolinolato

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：Melaniemei

【摘 要】

：

Bis(8-quinolinolato)zirconium dichloride (Ox)2ZrCl2 (Ox- = 8-quinolinolato) was foundactive for ethylene oligomerization with a high selectivity of 84～94% to C4～C

【作 者】

：

Ming Xing QIAN Mei WANG Hui WA 

【机 构】

：

State Key Laboratory of Fine Chemicals

【出 处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

Ethylene oligomerization low carbon olefins zirconium complex 8-hydroxyquinoline 

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论文部分内容阅读

Bis(8-quinolinolato)zirconium dichloride (Ox)2ZrCl2 (Ox- = 8-quinolinolato) was foundactive for ethylene oligomerization with a high selectivity of 84～94% to C4～C10 olefins at70～100℃ under the pressure of 1.8 MPa using Et2AlCl as a co-catalyst (Al/Zr = 60).

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