配位体交换色谱拆分外消旋α-氨基酸的研究,是苏联学者Davankov等早于七十年代初业已开始的,至今这一方面的研究还很活跃。对用于光学拆分的高分子载体来说,如何得到具有手性识别环境的手性高分子是重要的问题。作者曾经做了手性配体聚合物的合成及用其拆分DL-氨基酸的研究。在我们过去的工作中,用手性树脂Ⅰ、Ⅱ的铜(Ⅱ)络合物去拆 Ligand exchange chromatography resolution of racemic α-amino acid research, the Soviet scholar Davankov et al as early as the early 1970s has already begun, so far the study is still very active. How to obtain a chiral polymer with a chiral recognition environment is an important issue for polymeric carriers used for optical resolution. The authors have done the synthesis of chiral ligand polymers and the resolution of DL-amino acids. In our previous work, the copper (II) complexes of chiral resins I and II were deblocked