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从充放电性能、晶体结构等方面考察了包括粉末状的ZnO、脉冲激光沉积方法制备的ZnO 薄膜和含锌混合氧化物薄膜的电化学性质.结果表明,ZnO粉末制备的电极的嵌入容量随退火温度 的升高而增大,掺入其他氧化物可以明显改善ZnO 薄膜的电化学性能,在Ar气氛中,基片温度为 400℃时,沉积的靶子成分为Zn:B:P:Al=1:1:05:05(摩尔比)的含锌混合氧化物薄膜具有较 高的可逆容量,且循环性能良好.
The electrochemical properties of ZnO thin films and zinc-containing mixed oxide thin films prepared by pulsed laser deposition, including powdery ZnO, were investigated from charge-discharge performance and crystal structure. The results show that the insertion capacity of ZnO powders increases with the increase of annealing temperature. The addition of other oxides can obviously improve the electrochemical performance of ZnO thin films. In Ar atmosphere, when the substrate temperature is 400 ℃, The zinc-containing mixed oxide film having a target composition of Zn: B: P: Al = 1: 1: 05: 05 (molar ratio) has high reversible capacity and good cycle performance.