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首先用有机胺通过离子交换反应对层状粘土进行改性,然后将已改性的有机粘土作 为增强介质与通用型不饱和聚酯树脂合成了有机/无机纳米复合材料.利用FT-IR、XRD、 Instron等测试手段对其结构和性能进行了表征,并对影响材料形成的各种因素进行了讨论. 结果表明,经有机胺处理的粘土晶层间距得到了膨胀,而且复合材料的 XRD曲线中布拉 格衍射峰消失,说明粘土晶层已基本被聚合物撑开,形成层离型纳米复合材料.复合材料 的力学性能明显增强,仅含有3%(质量分数)处理土的复合材料,其抗冲击强度提高3倍.
Firstly, the layered clay was modified by ion exchange reaction with organic amine, and then the organic / inorganic nanocomposites were synthesized by using the modified organoclay as reinforcing medium and general-purpose unsaturated polyester resin. The structure and properties of the materials were characterized by FT-IR, XRD and Instron. The factors affecting the formation of materials were also discussed. The results show that the distance between the organic amine-treated clay grains expands, and the X-ray diffraction (XRD) of the composites disappears in the Bragg diffraction peaks, indicating that the clay layer has been basically opened by the polymer to form a delaminated nanocomposite. The mechanical properties of the composites were significantly enhanced. The composites containing only 3% (mass fraction) treated soil showed a threefold improvement in impact strength.