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The g-factors of the rotational states along the positive parity yrast band in even-even nuclei 84Zr were measured up to a spin I = 16+ by a transient magnetic field-ion implanted perturbed angular distribution method and calculated by a cranking shell model. A peak structure of the g-factors has been observed for the first time. The measured g-factors confirm the mixed configuration of proton and neutron alignments.