^31p NMR and ESI-MS Studies on Some Intermediates of the Peptide Coupling Reagents Triphenyl-chlorop

来源 :中国化学快报：英文版 | 被引量 : 0次 | 上传用户：rockykimi81

【摘要】

：

The intermediates of the Appel coupling reagents were studied in acetonitrile,dimethoxyethane and dioxane by 31P NMR, C NMR spectrum and ESI-MS. In dioxane a ne

【作者】

：

GuoTANG GuiJiZHOU FengNI LiMin

【机构】

：

TheKeyLaboratoryforChemicalBiologyofFujianProvince,TheKeylaboratoryforBioorganicPhosphorusChemistrya

【出处】

：

中国化学快报：英文版

【发表日期】

：

2005年3期

【关键词】

：

中间体缩氨酸耦合试剂三苯基-氯正膦六氯乙烷 PNMR ESI-MS 五磷化合物 Triphenylphosphine hexachloroethane

【基金项目】

：

Technology，Technology

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

The intermediates of the Appel coupling reagents were studied in acetonitrile,dimethoxyethane and dioxane by 31P NMR, C NMR spectrum and ESI-MS. In dioxane a new high coordinated phosphorous compound with 31p NMR shift at -39 ppm was observed. The ESI-MS

其他文献

螺旋CT颞骨三维重建及计算机辅助模拟耳科手术技术

<正> 颞骨内部结构精细,毗邻关系复杂,不仅该部位手术难度高,同时对该部位的应用解剖学研究比较棘手,临床教学讲解和图示很难表达清楚。采用螺旋CT三维成像技术将二维图像转

期刊

螺旋CT颞骨三维重建耳科手术模拟

劳应勋厅长在全省建设系统宣传贯彻《建设工程安全生产管理条例》电视电话会议上提出：从严查处事故强化责任追究

期刊

《建设工程安全生产管理条例》电视电话会议安全管理监督管理施工企业

Two New Xanthones from Polygala crotalarioides

Two new xanthones, 1, 6, 8-trihydroxy-2, 3-methylenedioxyxanthone 1 and 1, 4-dihydroxy-6, 7-methylenedioxyxanthone 2, were isolated from the roots of Polygala c

期刊

远志生物活性植物抗糖尿病药物分子结构光谱olygala crotalarioides Polygalaceae xanthones.

Synthesis of Nitrogen-containing Cyclopeptides from N-Terminal Lysine Precursor on Solid Supports

Three synthetic routes for the preparation of nitrogen containing cyclic compounds have been developed, in which the assembling of Fomc-Lys(Boc) residue at N-te

期刊

氮化合物循环酶固相合成方法Local-cyclic peptides intramolecular cyclization solid-phase

新法规：广告将成购房合同要约

期刊

商品房商品房价格广告购房合同法规

良、恶性胸腺瘤的CT诊断

本文通过对良，恶性胸腺瘤的ＣＴ特征分析，试图提高对二者ＣＴ鉴别诊断的准确性。材料和方法：回顾性地分析经手术病理证实的胸腺瘤，其中良性１４例，恶性１９例。结果：良性胸腺瘤平均直矩４．５ｃｍ，呈类圆形。

期刊

诊断胸腺瘤CTDiagnosis Thymoma

The First Total Synthesis of Triprenylquinone and Hydroquinones

First total synthesis of triprenylquinone and hydroquinones, three naturally occurring compound 1, 2 and (±) 3, have been achieved from readily available 2

期刊

对苯二酚合成方法衍生物结构表征Sesquiterpene triprenylquinones and hydroquinones total synt

建立特许经营制度政府和企业须建立良好的伙伴关系——建设部城建司司长李东序谈市政公用市场化与特许经营

期刊

李东序建设部城建司市政建设企业经营城市管网城市化人物专访

Reduction of 1-Deoxy-13-oxotaxanes

Reduction of 1-deoxy-13-oxotaxanes has been studied under different reaction conditions.Some interesting reactions were reported.

期刊

1-脱氧-13-氧紫杉醇还原反应抗癌活性紫杉醇Paclitaxel taxane reduction.

An Efficient Synthesis of Cyclopeptides Bridged with Aliphatic-aryl Ether Bond

Based on the pseudo-dilution effect (PDE) on solid support, three cyclopeptides with an aliphatic-aryl ether bond as the bridge were synthesized via SN2 reactio

期刊

苯甲酰甲基酯合成方法固相分子Intramolecular SN2 reaction cyclopeptide solid-phase organic

^31p NMR and ESI-MS Studies on Some Intermediates of the Peptide Coupling Reagents Triphenyl-chlorop

与本文相关的学术论文