【摘 要】
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Based on the redox reactions of Togni-Ⅱ reagent and thiols,a thiol-tuned selective functionalization of unactivated olefins was dis-closed.In combination with aryl thiols,stoichiometric amount of Togni-Ⅱ reagent prompted a hydrotrifluoromethylation of alk
【机 构】
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Hubei Key Laboratory of Natural Medicinal Chemistry and Resource Evaluation,School of Pharmacy,Huazh
论文部分内容阅读
Based on the redox reactions of Togni-Ⅱ reagent and thiols,a thiol-tuned selective functionalization of unactivated olefins was dis-closed.In combination with aryl thiols,stoichiometric amount of Togni-Ⅱ reagent prompted a hydrotrifluoromethylation of alkenes,in which,aryl thiols played as reductant and hydrogen source;while by utilization of alkyl thiols,catalytic amount of Togni-Ⅱ reagent ini-tiated thiol-ene and thiol-yne reactions.The reported applications are characterized by their operational simplicity and wide func-tional group tolerance.
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